Having the practical hands-on on the MDM functionalities would definitely help.
And try to be thorough on the docs.informatica.com all materials for MDM starting with 10.2 version.
Sathiesh M | Infa GCS-MDM
Below are the areas which we need to go over,
The MDM Data Model
Configuring the Stage Process, the Load Process, Fuzzy Matching
MDM Entity 360
The user interface, data cleansing and managing data.
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This for 10.3, However you can take this as a reference,