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if you're an employee of an Informatica partner company, then I suggest you register on the Partner Portal (https://parc.informatica.com/partners/); once your application has been accepted by Informatica Partner Management, you can sign up for tons of free online trainings; there will be something like IDQ - First Steps or IDQ Development Level 1 or something like that.
As an employee of a customer, there are basically two choices for you: either start by looking at the YouTube channel of Informatica, there should be tons of tutorials available there; or you take a "formal" training from Informatica University.
For the moment I would leave out DVO for a simple reason: DVO uses Informatica PowerCenter under the hood to perform its tasks; as you don't have any experience with PowerCenter, you might feel overwhelmed by the breadth of details you sometimes have to cater for.
So my personal suggestion is this:
1. Get a formal training of take a look at some YouTube tutorial for IDQ.
2. Once you feel halfway comfortable with IDQ, do the same for DVO.
Regards and welcome to this wonderful crazy world,